Tricarbonylchlorido{N-[2-(diphenylphosphino)benzylidene] benzylamine-N,P}rhenium(I) dichloromethane solvate

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Abstract

In the crystal structure of the title compound, [ReCl-(C26H22NP)(CO)3]CH2Cl2, the ReI atom exhibits a distorted octahedral environment defined by a facial arrangement of three carbonyl groups, a Cl atom and an N-[2-(diphenylphosphino)benzylidene]benzylamine ligand. The compound crystallizes with one CH2Cl2 molecule per asymmetric unit. The benzylamine ligand and the ReI centre form a non-planar six-membered chelate ring.
Original languageEnglish
Pages (from-to)m313
Number of pages14
JournalActa Crystallographica Section E
Volume64
Issue number2
DOIs
Publication statusPublished - 09 Jan 2008

Fields of science

  • 103 Physics, Astronomy
  • 104003 Inorganic chemistry
  • 204 Chemical Process Engineering
  • 104016 Photochemistry
  • 104021 Structural chemistry
  • 106032 Photobiology
  • 106002 Biochemistry
  • 210006 Nanotechnology
  • 107 Other Natural Sciences
  • 211908 Energy research
  • 301904 Cancer research
  • 301305 Medical chemistry
  • 105904 Environmental research

JKU Focus areas

  • Nano-, Bio- and Polymer-Systems: From Structure to Function
  • Engineering and Natural Sciences (in general)

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