Tetrakis(triphenylarsine)copper(I) hexafluorophosphate

Günther Knör; Thomas Kern; Uwe Monkowius; Manfred Zabel

doi:10.1107/S1600536807064458

Tetrakis(triphenylarsine)copper(I) hexafluorophosphate

Günther Knör, Thomas Kern, Uwe Monkowius, Manfred Zabel

Institute of Inorganic Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the crystal structure of the title compound, [{(C6H5)3As}4Cu][PF6], the copper atoms are coordinated by four arsenic atoms of triphenylarsine ligands within a tetrahedron. The complex cations are disposed about crystallographic threefold axes with the metal ion lying on a special position of site symmetry 3. Therefore, one of the arsine ligands is crystallographically inequivalent to the other three. The Cu-As bond of the independent arsine ligand is shorter than the Cu-As bonds of the three symmetry-related arsine ligands.

Original language	English
Pages (from-to)	m99
Number of pages	1
Journal	Acta Crystallographica Section E
Volume	64
Issue number	1
DOIs	https://doi.org/10.1107/S1600536807064458
Publication status	Published - 2008

Fields of science

104003 Inorganic chemistry

Access to Document

10.1107/S1600536807064458

Cite this

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title = "Tetrakis(triphenylarsine)copper(I) hexafluorophosphate",

abstract = "In the crystal structure of the title compound, [{(C6H5)3As}4Cu][PF6], the copper atoms are coordinated by four arsenic atoms of triphenylarsine ligands within a tetrahedron. The complex cations are disposed about crystallographic threefold axes with the metal ion lying on a special position of site symmetry 3. Therefore, one of the arsine ligands is crystallographically inequivalent to the other three. The Cu-As bond of the independent arsine ligand is shorter than the Cu-As bonds of the three symmetry-related arsine ligands.",

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year = "2008",

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journal = "Acta Crystallographica Section E",

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T1 - Tetrakis(triphenylarsine)copper(I) hexafluorophosphate

AU - Knör, Günther

AU - Kern, Thomas

AU - Monkowius, Uwe

AU - Zabel, Manfred

PY - 2008

Y1 - 2008

N2 - In the crystal structure of the title compound, [{(C6H5)3As}4Cu][PF6], the copper atoms are coordinated by four arsenic atoms of triphenylarsine ligands within a tetrahedron. The complex cations are disposed about crystallographic threefold axes with the metal ion lying on a special position of site symmetry 3. Therefore, one of the arsine ligands is crystallographically inequivalent to the other three. The Cu-As bond of the independent arsine ligand is shorter than the Cu-As bonds of the three symmetry-related arsine ligands.

AB - In the crystal structure of the title compound, [{(C6H5)3As}4Cu][PF6], the copper atoms are coordinated by four arsenic atoms of triphenylarsine ligands within a tetrahedron. The complex cations are disposed about crystallographic threefold axes with the metal ion lying on a special position of site symmetry 3. Therefore, one of the arsine ligands is crystallographically inequivalent to the other three. The Cu-As bond of the independent arsine ligand is shorter than the Cu-As bonds of the three symmetry-related arsine ligands.

U2 - 10.1107/S1600536807064458

DO - 10.1107/S1600536807064458

M3 - Article

SN - 2056-9890

VL - 64

SP - m99

JO - Acta Crystallographica Section E

JF - Acta Crystallographica Section E

IS - 1

ER -