Abstract
Two 1,8-naphthyridine (nap) metal complexes (nap)ReI(CO)3Cl (1) and [(nap)CuI(DPEPhos)]PF6 (2) were synthesized and characterized by NMR-, emission, and absorption spectroscopy, elemental analysis, mass spectrometry, and X-ray structural analysis. In both complexes, the nap ligand coordinates with both N atoms to the metal centre in a bidentate manner. 1 and 2 exhibit a broad phosphorescence in solid state at T = 300 K, which is completely quenched in solution at r.t. In addition, the gas-phase structures of both complexes were optimized at the B3LYP/6-31G(d,p) level of theory.
| Original language | English |
|---|---|
| Pages (from-to) | 1473-1477 |
| Number of pages | 5 |
| Journal | Inorganic Chemistry Communications |
| Volume | 10 |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - 2007 |
Fields of science
- 103 Physics, Astronomy
- 104003 Inorganic chemistry
- 204 Chemical Process Engineering
- 104016 Photochemistry
- 104021 Structural chemistry
- 106032 Photobiology
- 106002 Biochemistry
- 210006 Nanotechnology
- 107 Other Natural Sciences
- 211908 Energy research
- 301904 Cancer research
- 301305 Medical chemistry
- 105904 Environmental research
JKU Focus areas
- Nano-, Bio- and Polymer-Systems: From Structure to Function
- Engineering and Natural Sciences (in general)