Abstract
Orange red crystals of the new compound [Me4N]2[W2O2(?-S2)(eta2-S2)4].MeCN were obtained from the reaction of a solution of [Me4N]2[WOS3]in MeCN with solid AuCN at room temperature. They are monoclinic, space group P21/n, with a=9.264(2), b=17.736(3), c=18.742(5)Ä, beta=95.19(1)?; Z=4. The crystal structure was determined from single crystal diffractometer data (MoKalpha-radiation) and refined to R=0.050 (2955 reflections, 221 variable parameters). It is characterized by binuclear complex anions
Original language | English |
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Pages (from-to) | 1318-1322 |
Number of pages | 5 |
Journal | Zeitschrift für Naturforschung B: A Journal of Chemical Sciences |
Volume | 54 |
Issue number | 10 |
DOIs | |
Publication status | Published - 1999 |
Fields of science
- 103040 Photonics
- 104 Chemistry
- 104003 Inorganic chemistry
- 104008 Catalysis
- 104011 Materials chemistry
- 104015 Organic chemistry
- 104016 Photochemistry
- 104021 Structural chemistry
- 106 Biology
- 106002 Biochemistry
- 106032 Photobiology
- 107002 Bionics
- 209001 Biocatalysis
- 209004 Enzyme technology
- 210002 Nanobiotechnology
- 210005 Nanophotonics
- 211908 Energy research
- 211915 Solar technology
- 301114 Cell biology
- 301305 Medical chemistry
- 301904 Cancer research