Synthesis and Structural Characterization of [Me4N]2[W2O2(m-S)(h2-S2)4].MeCN a novel oxo-thiotungstate(VI)

A. B. M. Shamsur Rahman, Herbert Boller, Kurt O. Klepp

Research output: Contribution to journalArticlepeer-review

Abstract

Orange red crystals of the new compound [Me4N]2[W2O2(?-S2)(eta2-S2)4].MeCN were obtained from the reaction of a solution of [Me4N]2[WOS3]in MeCN with solid AuCN at room temperature. They are monoclinic, space group P21/n, with a=9.264(2), b=17.736(3), c=18.742(5)Ä, beta=95.19(1)?; Z=4. The crystal structure was determined from single crystal diffractometer data (MoKalpha-radiation) and refined to R=0.050 (2955 reflections, 221 variable parameters). It is characterized by binuclear complex anions
Original languageEnglish
Pages (from-to)1318-1322
Number of pages5
JournalZeitschrift für Naturforschung B: A Journal of Chemical Sciences
Volume54
Issue number10
DOIs
Publication statusPublished - 1999

Fields of science

  • 103040 Photonics
  • 104 Chemistry
  • 104003 Inorganic chemistry
  • 104008 Catalysis
  • 104011 Materials chemistry
  • 104015 Organic chemistry
  • 104016 Photochemistry
  • 104021 Structural chemistry
  • 106 Biology
  • 106002 Biochemistry
  • 106032 Photobiology
  • 107002 Bionics
  • 209001 Biocatalysis
  • 209004 Enzyme technology
  • 210002 Nanobiotechnology
  • 210005 Nanophotonics
  • 211908 Energy research
  • 211915 Solar technology
  • 301114 Cell biology
  • 301305 Medical chemistry
  • 301904 Cancer research

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