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Standard electrode potentials of M+|M couples in non-aqueous solvents (molecular liquids)

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Abstract

Electrode potentials referred to the standard hydrogen electrode (SHE) as reference were derived from polarographic (cyclovoltametric) and potentiometric measurements providing new data for up to forty non-aqueous solvents. Conversion to the SHE was based on the bis(biphenylchromium assumption. Comparison with data obtained from the assumption of a negligible liquid junction potential and from solubility studies in connection with the tetraphenylarsonium tetraphenylborate assumption is made.
Original languageEnglish
Pages (from-to)103-108
Number of pages6
JournalJournal of Molecular Liquids
Volume156
Issue number1
DOIs
Publication statusPublished - 15 Sept 2010

Fields of science

  • 104005 Electrochemistry
  • 104006 Solid state chemistry
  • 104014 Surface chemistry
  • 104017 Physical chemistry
  • 105113 Crystallography
  • 105116 Mineralogy
  • 503013 Subject didactics of natural sciences
  • 204 Chemical Process Engineering
  • 204001 Inorganic chemical technology
  • 205016 Materials testing
  • 210006 Nanotechnology
  • 211104 Metallurgy

JKU Focus areas

  • Engineering and Natural Sciences (in general)

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