Abstract
By exploiting an established on-surface metallation strategy, we address the ability of the corrolic macrocycle to stabilise transition metal ions in high-valent (III) oxidation states in metal-supported molecular layers. This approach offers a route to engineer adsorbed metal complexes that cannot be easily fabricated by organic synthesis methods and bear a vacant axial coordination site for catalytic conversions.
| Original language | English |
|---|---|
| Pages (from-to) | 11219-11222 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 56 |
| Issue number | 76 |
| DOIs | |
| Publication status | Published - 28 Sept 2020 |
Fields of science
- 104 Chemistry
- 104021 Structural chemistry
- 104026 Spectroscopy
- 104015 Organic chemistry
- 104017 Physical chemistry
- 106002 Biochemistry
- 106041 Structural biology
- 301305 Medical chemistry
- 302043 Magnetic resonance imaging (MRI)
JKU Focus areas
- Sustainable Development: Responsible Technologies and Management
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