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Abstract
Waterborne epoxy varnishes are essential for electrical steel laminates used in
electric engines or generators. Two varnish formulations based on bisphenol-A-
diglycidylether and dicyandiamide with an epoxy equivalent weight (EEW) of
~ 500 and ~ 900 g/mol were investigated. Thin specimens were prepared by con-
secutive coating and solvent evaporation followed by final curing. Glass transi-
tion temperatures (T g) of 89 °C (EEW-900) and 101 °C (EEW-500) were deduced
by dynamic mechanical analysis (DMA). The lower T g value was attributed to
the higher EEW and a lower network density. Moreover, master curves along
with Williams–Landel–Ferry and Prony series parameters were generated. By
digital image correlation (DIC)-assisted tensile testing of single epoxy films at
temperatures from 30 to 150 °C, a significant drop in tensile modulus from 2600
to 10 MPa and a rise in Poisson’s ratio from 0.35 to 0.47 was ascertained. The
implemented finite element model (FEM) showed a good agreement with the
experimental data.
electric engines or generators. Two varnish formulations based on bisphenol-A-
diglycidylether and dicyandiamide with an epoxy equivalent weight (EEW) of
~ 500 and ~ 900 g/mol were investigated. Thin specimens were prepared by con-
secutive coating and solvent evaporation followed by final curing. Glass transi-
tion temperatures (T g) of 89 °C (EEW-900) and 101 °C (EEW-500) were deduced
by dynamic mechanical analysis (DMA). The lower T g value was attributed to
the higher EEW and a lower network density. Moreover, master curves along
with Williams–Landel–Ferry and Prony series parameters were generated. By
digital image correlation (DIC)-assisted tensile testing of single epoxy films at
temperatures from 30 to 150 °C, a significant drop in tensile modulus from 2600
to 10 MPa and a rise in Poisson’s ratio from 0.35 to 0.47 was ascertained. The
implemented finite element model (FEM) showed a good agreement with the
experimental data.
| Original language | English |
|---|---|
| Pages (from-to) | 10353–10368 |
| Number of pages | 16 |
| Journal | Journal of Materials Science |
| Volume | 60 |
| Issue number | 25 |
| DOIs | |
| Publication status | Published - 16 Jun 2025 |
Fields of science
- 205 Materials Engineering
- 205004 Functional materials
- 205016 Materials testing
- 103023 Polymer physics
- 205013 Failure analysis
- 205019 Material sciences
- 211909 Energy technology
- 205011 Polymer engineering
JKU Focus areas
- Sustainable Development: Responsible Technologies and Management
Projects
- 1 Active
-
CDL-AgePol
Wallner, G. (PI)
01.09.2020 → 31.08.2027
Project: Funded research › Other mainly public funds