Photochemical Synthesis of cis,trans,cis-1,2,3,4-Tetrakis(diphenylphosphanyl)buta-1,3-diene and its Metal Coordination

Johannes Prock; Katharina Ehrmann; Wolfgang Viertl; Richard Pehn; Johann Pann; Helena Roithmeyer; Marvin Bendig; Alba Rodriguez Villalón; Holger Kopacka; Alexander Dumfort; Werner Oberhauser; Simon Clausing; Günther Knör; Peter Brüggeller

doi:10.1002/ejic.201800804

Photochemical Synthesis of cis,trans,cis-1,2,3,4-Tetrakis(diphenylphosphanyl)buta-1,3-diene and its Metal Coordination

Johannes Prock, Katharina Ehrmann, Wolfgang Viertl, Richard Pehn, Johann Pann, Helena Roithmeyer, Marvin Bendig, Alba Rodriguez Villalón, Holger Kopacka, Alexander Dumfort, Werner Oberhauser (Editor), Simon Clausing, Günther Knör (Editor), Peter Brüggeller (Editor)

Institute of Inorganic Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

An intramolecular photochemical reaction between 1,2-transbis(diphenylphosphanyl)ethene and 1,2-bis(diphenylphosphanyl) acetylene within a dimetallic Pt(II) complex gave selectively cis,trans,cis-1,2,3,4-tetrakis(diphenylphosphanyl)buta-1,3-diene. Its bis-chelating nature makes it suitable to access bimetallic chromophores applicable for the photochemical hydrogen production.

Original language	English
Pages (from-to)	4962-4971
Number of pages	10
Journal	European Journal of Inorganic Chemistry
Issue number	46
DOIs	https://doi.org/10.1002/ejic.201800804
Publication status	Published - 2018

Fields of science

211908 Energy research
211915 Solar technology
104 Chemistry
104011 Materials chemistry
104016 Photochemistry
104021 Structural chemistry
104003 Inorganic chemistry
104008 Catalysis
104015 Organic chemistry

JKU Focus areas

Nano-, Bio- and Polymer-Systems: From Structure to Function
Engineering and Natural Sciences (in general)

Access to Document

10.1002/ejic.201800804

Cite this

Prock, J., Ehrmann, K., Viertl, W., Pehn, R., Pann, J., Roithmeyer, H., Bendig, M., Rodriguez Villalón, A., Kopacka, H., Dumfort, A., Oberhauser, W. (Ed.), Clausing, S., Knör, G. (Ed.), & Brüggeller, P. (Ed.) (2018). Photochemical Synthesis of cis,trans,cis-1,2,3,4-Tetrakis(diphenylphosphanyl)buta-1,3-diene and its Metal Coordination. European Journal of Inorganic Chemistry, (46), 4962-4971. https://doi.org/10.1002/ejic.201800804

@article{f4c5e4ed357041d5bb4ccfc6e5e61c88,

title = "Photochemical Synthesis of cis,trans,cis-1,2,3,4-Tetrakis(diphenylphosphanyl)buta-1,3-diene and its Metal Coordination",

abstract = "An intramolecular photochemical reaction between 1,2-transbis(diphenylphosphanyl)ethene and 1,2-bis(diphenylphosphanyl) acetylene within a dimetallic Pt(II) complex gave selectively cis,trans,cis-1,2,3,4-tetrakis(diphenylphosphanyl)buta-1,3-diene. Its bis-chelating nature makes it suitable to access bimetallic chromophores applicable for the photochemical hydrogen production.",

author = "Johannes Prock and Katharina Ehrmann and Wolfgang Viertl and Richard Pehn and Johann Pann and Helena Roithmeyer and Marvin Bendig and \{Rodriguez Villal{\'o}n\}, Alba and Holger Kopacka and Alexander Dumfort and Werner Oberhauser and Simon Clausing and G{\"u}nther Kn{\"o}r and Peter Br{\"u}ggeller",

year = "2018",

doi = "10.1002/ejic.201800804",

language = "English",

pages = "4962--4971",

journal = "European Journal of Inorganic Chemistry",

issn = "1099-0682",

publisher = "Wiley VCH-Verlag",

number = "46",

}

Prock, J, Ehrmann, K, Viertl, W, Pehn, R, Pann, J, Roithmeyer, H, Bendig, M, Rodriguez Villalón, A, Kopacka, H, Dumfort, A, Oberhauser, W (ed.), Clausing, S, Knör, G (ed.) & Brüggeller, P (ed.) 2018, 'Photochemical Synthesis of cis,trans,cis-1,2,3,4-Tetrakis(diphenylphosphanyl)buta-1,3-diene and its Metal Coordination', European Journal of Inorganic Chemistry, no. 46, pp. 4962-4971. https://doi.org/10.1002/ejic.201800804

TY - JOUR

T1 - Photochemical Synthesis of cis,trans,cis-1,2,3,4-Tetrakis(diphenylphosphanyl)buta-1,3-diene and its Metal Coordination

AU - Prock, Johannes

AU - Ehrmann, Katharina

AU - Viertl, Wolfgang

AU - Pehn, Richard

AU - Pann, Johann

AU - Roithmeyer, Helena

AU - Bendig, Marvin

AU - Rodriguez Villalón, Alba

AU - Kopacka, Holger

AU - Dumfort, Alexander

AU - Clausing, Simon

A2 - Oberhauser, Werner

A2 - Knör, Günther

A2 - Brüggeller, Peter

PY - 2018

Y1 - 2018

N2 - An intramolecular photochemical reaction between 1,2-transbis(diphenylphosphanyl)ethene and 1,2-bis(diphenylphosphanyl) acetylene within a dimetallic Pt(II) complex gave selectively cis,trans,cis-1,2,3,4-tetrakis(diphenylphosphanyl)buta-1,3-diene. Its bis-chelating nature makes it suitable to access bimetallic chromophores applicable for the photochemical hydrogen production.

AB - An intramolecular photochemical reaction between 1,2-transbis(diphenylphosphanyl)ethene and 1,2-bis(diphenylphosphanyl) acetylene within a dimetallic Pt(II) complex gave selectively cis,trans,cis-1,2,3,4-tetrakis(diphenylphosphanyl)buta-1,3-diene. Its bis-chelating nature makes it suitable to access bimetallic chromophores applicable for the photochemical hydrogen production.

UR - https://www.x-mol.com/paper/910958

U2 - 10.1002/ejic.201800804

DO - 10.1002/ejic.201800804

M3 - Article

SN - 1099-0682

SP - 4962

EP - 4971

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 46

ER -

Photochemical Synthesis of cis,trans,cis-1,2,3,4-Tetrakis(diphenylphosphanyl)buta-1,3-diene and its Metal Coordination

Abstract

Fields of science

JKU Focus areas

Access to Document

Other files and links

Artificial Photosynthesis: Solar Hydrogen Production using Multinuclear Metal Complexes

Cite this

Photochemical Synthesis of cis,trans,cis-1,2,3,4-Tetrakis(diphenylphosphanyl)buta-1,3-diene and its Metal Coordination

Abstract

Fields of science

JKU Focus areas

Access to Document

Other files and links

Projects

Artificial Photosynthesis: Solar Hydrogen Production using Multinuclear Metal Complexes

Cite this