Abstract
A single crystal structure refinement of Tl0.83V5S8 corroborates the centrosymmetric space group C2/m being most probable for TlV5S8 type phases. Diffuse X-ray scattering proves one-dimensional ordering of the thallium atoms within the not fully occupied channels of the structure. A model for the cation order based on a restricted, commensurate Frenkel-Kontorowa chain is proposed.
| Original language | English |
|---|---|
| Number of pages | 3 |
| Journal | Solid State Ionics |
| Publication status | Published - Feb 1988 |
Fields of science
- 103040 Photonics
- 104 Chemistry
- 104003 Inorganic chemistry
- 104008 Catalysis
- 104011 Materials chemistry
- 104015 Organic chemistry
- 104016 Photochemistry
- 104021 Structural chemistry
- 106 Biology
- 106002 Biochemistry
- 106032 Photobiology
- 107002 Bionics
- 209001 Biocatalysis
- 209004 Enzyme technology
- 210002 Nanobiotechnology
- 210005 Nanophotonics
- 211908 Energy research
- 211915 Solar technology
- 301114 Cell biology
- 301305 Medical chemistry
- 301904 Cancer research
