On the crystal chemistry of hollandite-like phases with TlV5S8 structure: The crystal structures of TlxTi5S8, TlxV5S8 and TlCr5S8)

Herbert Boller

doi:10.1016/0025-5408(87)90215-7

On the crystal chemistry of hollandite-like phases with TlV5S8 structure: The crystal structures of TlxTi5S8, TlxV5S8 and TlCr5S8)

Herbert Boller

Institute of Inorganic Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compounds are monoclinic, space group C2/m, Z=2 with the lattice constants (in Ä): a=17.859, b=3.433, c=8.804, beta=104.26? (TlxTi5S8) a=17.490, b=3.297, c=8.511, beta=103.95? (TlxV5S8) a=17.767, b=3.431, c=8.594, beta=104.68? (TlCr5S8) The crystal structures of TlxTi5S8 and TlxV5S8 were refined from single crystal data (R=4.3% and 3.7% respectively), and the centrosymmetry of the TlV5S8 type was proven.

Original language	English
Pages (from-to)	1499-1504
Number of pages	6
Journal	Materials Research Bulletin
Volume	22
Issue number	11
DOIs	https://doi.org/10.1016/0025-5408(87)90215-7
Publication status	Published - Jun 1987

Fields of science

103040 Photonics
104 Chemistry
104003 Inorganic chemistry
104008 Catalysis
104011 Materials chemistry
104015 Organic chemistry
104016 Photochemistry
104021 Structural chemistry
106 Biology
106002 Biochemistry
106032 Photobiology
107002 Bionics
209001 Biocatalysis
209004 Enzyme technology
210002 Nanobiotechnology
210005 Nanophotonics
211908 Energy research
211915 Solar technology
301114 Cell biology
301305 Medical chemistry
301904 Cancer research

Access to Document

10.1016/0025-5408(87)90215-7

Cite this

@article{0cbce75cf8cf4fc48af4dba7684e2407,

title = "On the crystal chemistry of hollandite-like phases with TlV5S8 structure: The crystal structures of TlxTi5S8, TlxV5S8 and TlCr5S8)",

abstract = "The title compounds are monoclinic, space group C2/m, Z=2 with the lattice constants (in {\"A}): a=17.859, b=3.433, c=8.804, beta=104.26? (TlxTi5S8) a=17.490, b=3.297, c=8.511, beta=103.95? (TlxV5S8) a=17.767, b=3.431, c=8.594, beta=104.68? (TlCr5S8) The crystal structures of TlxTi5S8 and TlxV5S8 were refined from single crystal data (R=4.3\% and 3.7\% respectively), and the centrosymmetry of the TlV5S8 type was proven.",

author = "Herbert Boller",

year = "1987",

month = jun,

doi = "10.1016/0025-5408(87)90215-7",

language = "English",

volume = "22",

pages = "1499--1504",

journal = "Materials Research Bulletin",

issn = "0025-5408",

number = "11",

}

TY - JOUR

T1 - On the crystal chemistry of hollandite-like phases with TlV5S8 structure: The crystal structures of TlxTi5S8, TlxV5S8 and TlCr5S8)

AU - Boller, Herbert

PY - 1987/6

Y1 - 1987/6

N2 - The title compounds are monoclinic, space group C2/m, Z=2 with the lattice constants (in Ä): a=17.859, b=3.433, c=8.804, beta=104.26? (TlxTi5S8) a=17.490, b=3.297, c=8.511, beta=103.95? (TlxV5S8) a=17.767, b=3.431, c=8.594, beta=104.68? (TlCr5S8) The crystal structures of TlxTi5S8 and TlxV5S8 were refined from single crystal data (R=4.3% and 3.7% respectively), and the centrosymmetry of the TlV5S8 type was proven.

AB - The title compounds are monoclinic, space group C2/m, Z=2 with the lattice constants (in Ä): a=17.859, b=3.433, c=8.804, beta=104.26? (TlxTi5S8) a=17.490, b=3.297, c=8.511, beta=103.95? (TlxV5S8) a=17.767, b=3.431, c=8.594, beta=104.68? (TlCr5S8) The crystal structures of TlxTi5S8 and TlxV5S8 were refined from single crystal data (R=4.3% and 3.7% respectively), and the centrosymmetry of the TlV5S8 type was proven.

UR - https://www.scopus.com/pages/publications/0023451984

U2 - 10.1016/0025-5408(87)90215-7

DO - 10.1016/0025-5408(87)90215-7

M3 - Article

SN - 0025-5408

VL - 22

SP - 1499

EP - 1504

JO - Materials Research Bulletin

JF - Materials Research Bulletin

IS - 11

ER -

On the crystal chemistry of hollandite-like phases with TlV5S8 structure: The crystal structures of TlxTi5S8, TlxV5S8 and TlCr5S8)

Abstract

Fields of science

Access to Document

Other files and links

Cite this