Abstract
The trinuclear complex [Me4N]3[(WOS3)2Ag].MeCN was prepd. by the reaction of [Me4N]2WOS3 with AgCN in MeCN at room temp. followed by slow crystn. in the refrigerator. It was characterized by IR and mass spectroscopy. It crystallizes in the orthorhombic space group Pnma (No. 62) with unit cell dimensions a = 19.648(7), b = 27.878(12), c = 11.494(3) .ANG., Z = 8. The crystal structure was detd. from single crystal diffractometer data (Mo-K radiation) and refined to R = 0.077. The structure is composed of mixed double layers contg. the linear trinuclear anion [(WOS3)2Ag]3- and cations sepd. by a layer formed by cations and solvating acetonitrile mols.
| Original language | English |
|---|---|
| Pages (from-to) | 867-870 |
| Number of pages | 4 |
| Journal | Zeitschrift für Naturforschung B: A Journal of Chemical Sciences |
| Volume | 61 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - 2006 |
Fields of science
- 103040 Photonics
- 104 Chemistry
- 104003 Inorganic chemistry
- 104008 Catalysis
- 104011 Materials chemistry
- 104015 Organic chemistry
- 104016 Photochemistry
- 104021 Structural chemistry
- 106 Biology
- 106002 Biochemistry
- 106032 Photobiology
- 107002 Bionics
- 209001 Biocatalysis
- 209004 Enzyme technology
- 210002 Nanobiotechnology
- 210005 Nanophotonics
- 211908 Energy research
- 211915 Solar technology
- 301114 Cell biology
- 301305 Medical chemistry
- 301904 Cancer research