Abstract
Orange-yellow plate-like crystals of the title compound were obtained from the reaction of [Me4N]2WO2S2 or [Me4N]WOS3 with CuCl and [Me4N]Cl in MeCN solution. They are hexagonal, space group P63cm (No. 185), with unit cell parameters a = 11.638(4)Ä, c = 17.970(7)Ä, Z = 2. The crystal structure was determined from single crystal X-ray diffraction data (MoKalpha-radiation) and refined to R = 0.049. The structure is characterized as an alternating packing of cubane-like [WOS3(CuCl)3Cl]3- and Cl- anions.
| Original language | English |
|---|---|
| Pages (from-to) | 2554-2557 |
| Number of pages | 4 |
| Journal | Zeitschrift für Anorganische und Allgemeine Chemie |
| Volume | 630 |
| Issue number | 13-14 |
| DOIs | |
| Publication status | Published - 2004 |
Fields of science
- 103040 Photonics
- 104 Chemistry
- 104003 Inorganic chemistry
- 104008 Catalysis
- 104011 Materials chemistry
- 104015 Organic chemistry
- 104016 Photochemistry
- 104021 Structural chemistry
- 106 Biology
- 106002 Biochemistry
- 106032 Photobiology
- 107002 Bionics
- 209001 Biocatalysis
- 209004 Enzyme technology
- 210002 Nanobiotechnology
- 210005 Nanophotonics
- 211908 Energy research
- 211915 Solar technology
- 301114 Cell biology
- 301305 Medical chemistry
- 301904 Cancer research
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