Abstract
Fibrous red crystals of the new compound K2TiS3 were obtained by reacting K2S, Ti and S at 1070 K. K2TiS3 is monoclinic, space group C2/c with a=11.667(6)Ä, b=8.325(4)Ä, c=6.494(4)Ä, beta=91.81(4)?, Z=4. The crystal structure was refined to a conventional residual of 0.070. The atomic arrangement is characterized by pseudo-one-dimensional [TiS3](2-)-chains formed by distorted TiS5 square pyramids sharing opposite edges of their basal planes. The structure - though closely related to that of Cs2TiS3 - is of a new type.
| Translated title of the contribution | K2TiS3, A New Thiotitanate(IV) with Pentacoordinate Titanium |
|---|---|
| Original language | German (Austria) |
| Number of pages | 4 |
| Journal | Zeitschrift für Naturforschung B: A Journal of Chemical Sciences |
| Publication status | Published - Aug 1991 |
Fields of science
- 103040 Photonics
- 104 Chemistry
- 104003 Inorganic chemistry
- 104008 Catalysis
- 104011 Materials chemistry
- 104015 Organic chemistry
- 104016 Photochemistry
- 104021 Structural chemistry
- 106 Biology
- 106002 Biochemistry
- 106032 Photobiology
- 107002 Bionics
- 209001 Biocatalysis
- 209004 Enzyme technology
- 210002 Nanobiotechnology
- 210005 Nanophotonics
- 211908 Energy research
- 211915 Solar technology
- 301114 Cell biology
- 301305 Medical chemistry
- 301904 Cancer research
