Influence of plasmon excitations in Au nanoparticles upon fluorescence and photostability of photosynthetic complexes

B. Krajnik, N. Czechowski, D. Piatkowski, S. Mackowski, E. Hofmann, S. Pichler, Wolfgang Johann Heiß

Research output: Contribution to journalArticlepeer-review

Abstract

Fluorescence spectroscopy is applied to study the influence of plasmon excitations in spherical Au nanoparticles on the optical properties of chlorophyll-containing light-harvesting complexes. The separation between the two nanostructures is controlled via silica layer with varied thickness. We observe strong increase of the emission intensity for a 12- nm-thick spacer and the increase is accompanied with shortening of the fluorescence lifetime, which allows us to sepa- rate contributions of absorption and emission rate enhancement. At the same time we find an increase of photobleaching. These findings are interpreted as a result of spectral overlap between plasmon resonance and chlorophyll fluorescence.
Original languageEnglish
Pages (from-to)1-7
Number of pages7
JournalOptics and Photonics Journal
Volume3
DOIs
Publication statusPublished - 2013

Fields of science

  • 103009 Solid state physics
  • 103021 Optics
  • 103011 Semiconductor physics
  • 103 Physics, Astronomy

JKU Focus areas

  • Engineering and Natural Sciences (in general)

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