Abstract
The influence of the concentration of the supporting electrolyte sodium perchlorate on the standard electrode reaction rate constants for the one-electron reduction of Eu(CF3SO3)3 on mercury in dimethylsulfoxide has been studied. The -values were derived from both ac polarography on the dropping mercury electrode and from cyclic voltammetry on a hanging mercury drop in a two electrode system. The ac data was evaluated by the Randles and the by Sluyters methods. The standard reaction rates from cyclic voltammetry were extracted via a simulation program. Densities, viscosities, specific resistances (resistivities) and double layer capacitances of the electrolytes were measured. Correlations between electrolyte properties and the ks-values were investigated. The standard electrode reaction rates were also treated within the Frumkin theory.
| Original language | English |
|---|---|
| Pages (from-to) | 367 - 373 |
| Number of pages | 7 |
| Journal | Journal of Electroanalytical Chemistry |
| Volume | 565 |
| Publication status | Published - 2004 |
Fields of science
- 104005 Electrochemistry
- 104006 Solid state chemistry
- 104014 Surface chemistry
- 104017 Physical chemistry
- 105113 Crystallography
- 105116 Mineralogy
- 503013 Subject didactics of natural sciences
- 204 Chemical Process Engineering
- 204001 Inorganic chemical technology
- 205016 Materials testing
- 210006 Nanotechnology
- 211104 Metallurgy