Topotactic oxidation of NaCrS2

Herbert Boller

doi:10.1016/s0167-2738(01)00720-2

Topotactic oxidation of NaCrS2

Herbert Boller

Institut für Anorganische Chemie

Publikation: Beitrag in Fachzeitschrift › Konferenzartikel › Begutachtung

Abstract

The topotactic deintercalation of NaCrS2 by I2 in refluxing acetonitrile and in a solid-vapor reaction at different temps. is studied. The resulting products are metastable CrS2-x (x 0.1) or stable Cr2S3 according to the reaction temp. Starting at 550, Cr2S3 is topotactically transformed to Cr2O3 in an O2-bearing Ar atm.

Originalsprache	Englisch
Seiten (von - bis)	53-56
Seitenumfang	4
Fachzeitschrift	Solid State Ionics
Volume	141-142
DOIs	https://doi.org/10.1016/s0167-2738(01)00720-2
Publikationsstatus	Veröffentlicht - 01 Mai 2001

Wissenschaftszweige

103040 Photonik
104 Chemie
104003 Anorganische Chemie
104008 Katalyse
104011 Materialchemie
104015 Organische Chemie
104016 Photochemie
104021 Strukturchemie
106 Biologie
106002 Biochemie
106032 Photobiologie
107002 Bionik
209001 Biokatalyse
209004 Enzymtechnologie
210002 Nanobiotechnologie
210005 Nanophotonik
211908 Energieforschung
211915 Solartechnik
301114 Zellbiologie
301305 Medizinische Chemie
301904 Krebsforschung

Zugriff auf Dokument

10.1016/s0167-2738(01)00720-2

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title = "Topotactic oxidation of NaCrS2",

abstract = "The topotactic deintercalation of NaCrS2 by I2 in refluxing acetonitrile and in a solid-vapor reaction at different temps. is studied. The resulting products are metastable CrS2-x (x 0.1) or stable Cr2S3 according to the reaction temp. Starting at 550, Cr2S3 is topotactically transformed to Cr2O3 in an O2-bearing Ar atm.",

author = "Herbert Boller",

year = "2001",

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doi = "10.1016/s0167-2738(01)00720-2",

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AU - Boller, Herbert

PY - 2001/5/1

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N2 - The topotactic deintercalation of NaCrS2 by I2 in refluxing acetonitrile and in a solid-vapor reaction at different temps. is studied. The resulting products are metastable CrS2-x (x 0.1) or stable Cr2S3 according to the reaction temp. Starting at 550, Cr2S3 is topotactically transformed to Cr2O3 in an O2-bearing Ar atm.

AB - The topotactic deintercalation of NaCrS2 by I2 in refluxing acetonitrile and in a solid-vapor reaction at different temps. is studied. The resulting products are metastable CrS2-x (x 0.1) or stable Cr2S3 according to the reaction temp. Starting at 550, Cr2S3 is topotactically transformed to Cr2O3 in an O2-bearing Ar atm.

UR - https://www.scopus.com/pages/publications/17744408122

U2 - 10.1016/s0167-2738(01)00720-2

DO - 10.1016/s0167-2738(01)00720-2

M3 - Conference article

SN - 0167-2738

VL - 141-142

SP - 53

EP - 56

JO - Solid State Ionics

JF - Solid State Ionics

ER -