[Me4N][Cu2(NCS)3] - a compound having a framework structure with large channels

R Dilshad; Kurt O. Klepp; Herbert Boller

doi:10.1016/j.solidstatesciences.2004.11.028

[Me4N][Cu2(NCS)3] - a compound having a framework structure with large channels

R Dilshad
, Kurt O. Klepp
, Herbert Boller

Institut für Anorganische Chemie

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

Abstract

Transparent colorless well shaped prismatic crystals of [Me4N][Cu2(NCS)3] were obtained by crystn. from a reaction mixt. of [Me4N]Cl, CuCl and KSCN in MeCN at room temp. The compd. was characterized by chem. anal. and IR spectroscopy. Its crystal structure was detd. by single crystal x-ray anal. It is tetragonal with unit cell dimensions a 11.164(4) .ANG. , c 10.638(5) .ANG. , space group P42cm, Z = 4. The anionic [Cu2(NCS)3]- partial structure forms a framework with large channels running parallel to the c axis and accommodating the org. cations.

Originalsprache	Englisch
Seiten (von - bis)	1230-1235
Seitenumfang	6
Fachzeitschrift	Solid State Sciences
Volume	7
Ausgabenummer	10
DOIs	https://doi.org/10.1016/j.solidstatesciences.2004.11.028
Publikationsstatus	Veröffentlicht - Okt. 2005

Wissenschaftszweige

103040 Photonik
104 Chemie
104003 Anorganische Chemie
104008 Katalyse
104011 Materialchemie
104015 Organische Chemie
104016 Photochemie
104021 Strukturchemie
106 Biologie
106002 Biochemie
106032 Photobiologie
107002 Bionik
209001 Biokatalyse
209004 Enzymtechnologie
210002 Nanobiotechnologie
210005 Nanophotonik
211908 Energieforschung
211915 Solartechnik
301114 Zellbiologie
301305 Medizinische Chemie
301904 Krebsforschung

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10.1016/j.solidstatesciences.2004.11.028

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title = "[Me4N][Cu2(NCS)3] - a compound having a framework structure with large channels",

abstract = "Transparent colorless well shaped prismatic crystals of [Me4N][Cu2(NCS)3] were obtained by crystn. from a reaction mixt. of [Me4N]Cl, CuCl and KSCN in MeCN at room temp. The compd. was characterized by chem. anal. and IR spectroscopy. Its crystal structure was detd. by single crystal x-ray anal. It is tetragonal with unit cell dimensions a 11.164(4) .ANG. , c 10.638(5) .ANG. , space group P42cm, Z = 4. The anionic [Cu2(NCS)3]- partial structure forms a framework with large channels running parallel to the c axis and accommodating the org. cations.",

author = "R Dilshad and Klepp, \{Kurt O.\} and Herbert Boller",

year = "2005",

month = oct,

doi = "10.1016/j.solidstatesciences.2004.11.028",

language = "English",

volume = "7",

pages = "1230--1235",

journal = "Solid State Sciences",

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T1 - [Me4N][Cu2(NCS)3] - a compound having a framework structure with large channels

AU - Dilshad, R

AU - Klepp, Kurt O.

AU - Boller, Herbert

PY - 2005/10

Y1 - 2005/10

N2 - Transparent colorless well shaped prismatic crystals of [Me4N][Cu2(NCS)3] were obtained by crystn. from a reaction mixt. of [Me4N]Cl, CuCl and KSCN in MeCN at room temp. The compd. was characterized by chem. anal. and IR spectroscopy. Its crystal structure was detd. by single crystal x-ray anal. It is tetragonal with unit cell dimensions a 11.164(4) .ANG. , c 10.638(5) .ANG. , space group P42cm, Z = 4. The anionic [Cu2(NCS)3]- partial structure forms a framework with large channels running parallel to the c axis and accommodating the org. cations.

AB - Transparent colorless well shaped prismatic crystals of [Me4N][Cu2(NCS)3] were obtained by crystn. from a reaction mixt. of [Me4N]Cl, CuCl and KSCN in MeCN at room temp. The compd. was characterized by chem. anal. and IR spectroscopy. Its crystal structure was detd. by single crystal x-ray anal. It is tetragonal with unit cell dimensions a 11.164(4) .ANG. , c 10.638(5) .ANG. , space group P42cm, Z = 4. The anionic [Cu2(NCS)3]- partial structure forms a framework with large channels running parallel to the c axis and accommodating the org. cations.

UR - https://www.scopus.com/pages/publications/25444483135

U2 - 10.1016/j.solidstatesciences.2004.11.028

DO - 10.1016/j.solidstatesciences.2004.11.028

M3 - Article

SN - 1293-2558

VL - 7

SP - 1230

EP - 1235

JO - Solid State Sciences

JF - Solid State Sciences

IS - 10

ER -